Ločevanje izomerov metamfetamina s pomočjo vinske kisline

Mr Good Cat

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@G.Patton splošno, ali ni bolj preprosto uporabiti d-vinsko kislino št. CAS 147-71-7, vendar v veliko manjših molskih razmerjih približno 1 (baza):0,2-0,5 (d-vinska kislina)? Natančna razmerja se lahko ocenijo s preprostim testom.
 

G.Patton

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Da, lahko uporabite d-vinsko kislino CAS št. 147-71-7, vendar je dražja in nekateri ljudje nimajo dostopa do nje. Primer je prikazan z najcenejšo in najpreprostejšo možnostjo.
 
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Bmth

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Res je, da ne proizvaja kristalov, ali lahko pomagate, da bi bil pravilen tartarat ali morda formula snovi 🙏
 

Bmth

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Bis Ali mi lahko posredujete navodila o postopku ali povezavo do postopka? Najlepša hvala. 🙏
 

Bmth

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HLlku3fb2X

Ali je to ta? Prosim, pomagajte tem strokovnjakom, ki so poskusili četrtič, ko sem dobil neuspeh. 🤣🤣
 
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G.Patton

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Jasno je povedano, katero snov morate uporabiti. Kakšno težavo imate?
 

OrgUnikum

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The main problem with this method is that one gets l-Meth, to be more precise one gets from slightly enriched l-Meth to predominantly l-Meth depending on how long one lets it crystallize out. The more time the more l-Meth is in the cristalline mass. When good stirring is employed the result will be even more l-meth in the crystals (in relation of course).
The good thing s that one gets pretty decent d-Meth fromm the mother liquor.

It does not matter if one uses l-tartaric or d-tartaric or d/l tartaric - it will always be l-Meth what crystallizes out most. It is completely different from Amphetamine btw. cannot be compared at all. I actually understood what is really going on only a short time ago and I fully understand why somebody might believe I am wrong, but well, I am not.

As I try not to criticize when I cannot offer an alternative, here it is:
7.84 g (0.0525 mol) racemic N-methylamphetamine and 9.73 g (0.0525 mol) racemic N-methylamphetamine hydrochloride were dissolved in 70 ml of abs. ethanol and 7.91 g (0.0525 mol) R,R tartaric acid (L-(+)-tartaric acid) in 56 ml of abs. ethanol.
Strong stirring for twenty two hours. room temperature, then the mixture is cooled in the fridge, the formed salt is filtered out and the mother liquor is worked up by A/B extraction and recrystallisation to yield almost exclusively d-Meth.

Its all in the literature. Just not in one place but a bit obfusicated.

Good luck
 

cruz

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Can we use ethanol contains denatonium for washing or in the crystallization stage? Denatonium in it won't make a problem?
 

cruz

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Can I use this tartaric acid? It's L(+)- tartaric acid. Seller said there 2 kinds of L tartaric acid. L (-) AND L(+). L(+) means dl tartaric acid.
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A
 

DREWJACK123

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How would the procedure differ if you had bought racemic cartel dope on the streets and want to separate isomers.i just got d,l tartaric acid I have all the reagents and just got a hot plate/magnetic stirrer. Would you just skip the first steam distillation step and go straight into freebasing and then adding the tartaric and ethanol? I got the ethanol from hand sanitizer and leeched out the glycerin with salt.it was already 70 percent so it should be at least 88 now. And when I'm precipitating the hcl salt does it not snow right away like a regular gas session. Do you just gas it then wait for it to precipitate I don't understand that part.
 

finch3523

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could you separate dex/levo amphetamine with tartaric acid first and then from the dex amphetamine create dex methamphetamine or would this not be advised?
 
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